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Literature DB >> 27819362

Properties and emerging applications of mechanically interlocked ligands.

James E M Lewis¹, Marzia Galli¹, Stephen M Goldup¹.

Abstract

Mechanically interlocked molecules have a long and rich history as ligands thanks to the key role coordination chemistry has played in the development of high yielding passive template syntheses of rotaxanes and catenanes. In this Feature Article, we highlight the effect of the mechanical bond on the properties of metal ions bound within the sterically hindered environment of the macrocycle cavity, and discuss the emerging applications of interlocked ligands in catalysis, sensing and supramolecular materials.

Entities: Chemical

Year: 2016 PMID： 27819362 DOI： 10.1039/c6cc07377h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

18 in total

1. Docking rings in a solid: reversible assembling of pseudorotaxanes inside a zirconium metal-organic framework.

Authors: Xia Li; Jialin Xie; Zhenglin Du; Long Jiang; Guangqin Li; Sanliang Ling; Kelong Zhu
Journal: Chem Sci Date: 2022-05-02 Impact factor: 9.969

2. Metastable doubly threaded [3]rotaxanes with a large macrocycle.

Authors: Jerald E Hertzog; Vincent J Maddi; Laura F Hart; Benjamin W Rawe; Phillip M Rauscher; Katie M Herbert; Eric P Bruckner; Juan J de Pablo; Stuart J Rowan
Journal: Chem Sci Date: 2022-04-20 Impact factor: 9.969

3. Anion-π Catalysis Enabled by the Mechanical Bond.

Authors: John R J Maynard; Bartomeu Galmés; Athanasios D Stergiou; Mark D Symes; Antonio Frontera; Stephen M Goldup
Journal: Angew Chem Int Ed Engl Date: 2022-02-03 Impact factor: 16.823

4. Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.

Authors: Alberto Martinez-Cuezva; Adrian Saura-Sanmartin; Tomas Nicolas-Garcia; Cristian Navarro; Raul-Angel Orenes; Mateo Alajarin; Jose Berna
Journal: Chem Sci Date: 2017-03-07 Impact factor: 9.825

5. Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket.

Authors: Alberto Martinez-Cuezva; Aurelia Pastor; Marta Marin-Luna; Carmen Diaz-Marin; Delia Bautista; Mateo Alajarin; Jose Berna
Journal: Chem Sci Date: 2020-11-11 Impact factor: 9.825

10. Synthesis of diamido-bridged bis-pillar[5]arenes and tris-pillar[5]arenes for construction of unique [1]rotaxanes and bis-[1]rotaxanes.

Authors: Ying Han; Li-Ming Xu; Cui-Yun Nie; Shuo Jiang; Jing Sun; Chao-Guo Yan
Journal: Beilstein J Org Chem Date: 2018-07-04 Impact factor: 2.883

Properties and emerging applications of mechanically interlocked ligands.

1. Docking rings in a solid: reversible assembling of pseudorotaxanes inside a zirconium metal-organic framework.

2. Metastable doubly threaded [3]rotaxanes with a large macrocycle.

3. Anion-π Catalysis Enabled by the Mechanical Bond.

4. Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.

5. Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket.

6. Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra.

7. Impact of mechanical bonding on the redox-switching of tetrathiafulvalene in crown ether-ammonium [2]rotaxanes.

8. Efficient Multicomponent Active Template Synthesis of Catenanes.

9. A Fluorescent Ditopic Rotaxane Ion-Pair Host.

10. Synthesis of diamido-bridged bis-pillar[5]arenes and tris-pillar[5]arenes for construction of unique [1]rotaxanes and bis-[1]rotaxanes.