Literature DB >> 27807893

Direct Catalytic Hydrogenation of Simple Amides: A Highly Efficient Approach from Amides to Amines and Alcohols.

Liyang Shi1, Xuefeng Tan1, Jiao Long1, Xiong Xiong1, Song Yang1, Peng Xue1, Hui Lv1,2, Xumu Zhang1.   

Abstract

A highly chemoselective and reactive direct catalytic reduction of various amides to amines and alcohols was developed by using a tetradentate ruthenium complex. The catalytic system showed excellent activity (turnover numbers up to 19 600) and great functional group tolerance under mild reaction conditions, compared to several bidentate and tridentate ruthenium-catalyzed systems.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alcohols; amides; amines; chemoselectivity; hydrogenation

Year:  2016        PMID： 27807893     DOI： 10.1002/chem.201604904

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  7 in total

1.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

2.  Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight.

Authors:  Sayan Kar; Michael Rauch; Amit Kumar; Gregory Leitus; Yehoshoa Ben-David; David Milstein
Journal:  ACS Catal       Date:  2020-04-21       Impact factor: 13.084

3.  Hydrogenative Depolymerization of Nylons.

Authors:  Amit Kumar; Niklas von Wolff; Michael Rauch; You-Quan Zou; Guy Shmul; Yehoshoa Ben-David; Gregory Leitus; Liat Avram; David Milstein
Journal:  J Am Chem Soc       Date:  2020-08-11       Impact factor: 15.419

4.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

5.  Multifaceted catalytic hydrogenation of amides via diverse activation of a sterically confined bipyridine-ruthenium framework.

Authors:  Takashi Miura; Masayuki Naruto; Katsuaki Toda; Taiki Shimomura; Susumu Saito
Journal:  Sci Rep       Date:  2017-05-16       Impact factor: 4.379

Review 6.  Homogeneous and heterogeneous catalytic reduction of amides and related compounds using molecular hydrogen.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Matthias Beller
Journal:  Nat Commun       Date:  2020-08-04       Impact factor: 14.919

7.  Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism.

Authors:  Thomas Leischner; Lluis Artús Suarez; Anke Spannenberg; Kathrin Junge; Ainara Nova; Matthias Beller
Journal:  Chem Sci       Date:  2019-10-08       Impact factor: 9.825
  7 in total

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