Fluorescent Properties and Kinetic Rate Constants of some Zn-Tetraarylporphyrins Formation in Acetonitrile.

The fluorescence quantum yield of the 5,10,15,20-tetraphenylporphyrin, 5,10,15,20-tetra(4-OH-phenyl)porphyrin, 5,10,15,20-tetra(4-Cl-phenyl)porphyrin, 5,10,15,20-tetra(4-NH2-phenyl)porphyrin and their complexes with Zn2+ have been determined and the kinetic rate constants of the porphyrins ligands complexation with Zn2+ in acetonitrile have been estimated. It was shown that the substituents on the tetrapyrrolic macrocycle periphery have a strong influence on the fluorescent and coordination properties of the investigated porphyrins.