Literature DB >> 27791342

Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones.

Marc Perez1, Saravanakumar Elangovan1, Anke Spannenberg1, Kathrin Junge1, Matthias Beller1.   

Abstract

For the first time an easily accessible and well-defined manganese N,N,N-pincer complex catalyzes the transfer hydrogenation of a broad range of ketones with good to excellent yields. This cheap earth abundant-metal based catalyst provides access to useful secondary alcohols without the need of hydrogen gas. Preliminary investigations to explore the mechanism of this transformation are also reported.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  homogeneous catalysis; ketones; manganese complex; pincer ligands; transfer hydrogenation

Mesh：

Substances：

Year:  2016        PMID： 27791342     DOI： 10.1002/cssc.201601057

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  9 in total

1.  A Manganese Nanosheet: New Cluster Topology and Catalysis.

Authors:  Uttam Chakraborty; Efrain Reyes-Rodriguez; Serhiy Demeshko; Franc Meyer; Axel Jacobi von Wangelin
Journal:  Angew Chem Int Ed Engl       Date:  2018-03-23       Impact factor: 15.336

2.  Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones.

Authors:  Oriol Martínez-Ferraté; Christophe Werlé; Giancarlo Franciò; Walter Leitner
Journal:  ChemCatChem       Date:  2018-10-11       Impact factor: 5.686

3.  Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols.

Authors:  Subrata Chakraborty; Prosenjit Daw; Yehoshoa Ben David; David Milstein
Journal:  ACS Catal       Date:  2018-10-02       Impact factor: 13.084

4.  A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.

Authors:  María Andérez-Fernández; Lydia K Vogt; Steffen Fischer; Wei Zhou; Haijun Jiao; Marcel Garbe; Saravanakumar Elangovan; Kathrin Junge; Henrik Junge; Ralf Ludwig; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-02       Impact factor: 15.336

5.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

6.  Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes.

Authors:  Federica Bertini; Mathias Glatz; Nikolaus Gorgas; Berthold Stöger; Maurizio Peruzzini; Luis F Veiros; Karl Kirchner; Luca Gonsalvi
Journal:  Chem Sci       Date:  2017-05-04       Impact factor: 9.825

7.  Chemoselective Hydrogenation of Aldehydes under Mild, Base-Free Conditions: Manganese Outperforms Rhenium.

Authors:  Mathias Glatz; Berthold Stöger; Daniel Himmelbauer; Luis F Veiros; Karl Kirchner
Journal:  ACS Catal       Date:  2018-04-02       Impact factor: 13.084

8.  Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C1 Source.

Authors:  Akash Kaithal; Pit van Bonn; Markus Hölscher; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-28       Impact factor: 15.336

9.  Efficient and Practical Transfer Hydrogenation of Ketones Catalyzed by a Simple Bidentate Mn-NHC Complex.

Authors:  Robbert van Putten; Joeri Benschop; Vincent J de Munck; Manuela Weber; Christian Müller; Georgy A Filonenko; Evgeny A Pidko
Journal:  ChemCatChem       Date:  2019-07-08       Impact factor: 5.686
  9 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.