Literature DB >> 27791310

A Rigid Nested Metal-Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions.

Qiang Gao1,2, Jian Xu2, Dapeng Cao3, Ze Chang2, Xian-He Bu1,2.   

Abstract

We herein report a rigid nested metal-organic framework (MOF) featuring a unique thermoresponsive gating adsorption behavior, which, in contrast to any known flexibility modes for stimuli-responsive MOFs, depends on the thermal motion of the extra-framework counterions. In addition, this MOF also exhibits adsorption selectivity of CO2 over N2 , H2 , and Ar at 273 K, thus enabling a strategic separation and encapsulation of CO2 .
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  counterions; metal-organic frameworks; rigid nested metal-organic framework; robust dynamics; thermoresponsive gating effect

Year:  2016        PMID： 27791310     DOI： 10.1002/anie.201608250

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Design and Synthesis of Porous Nickel(II) and Cobalt(II) Cages.

Authors:  Aeri J Gosselin; Casey A Rowland; Krista P Balto; Glenn P A Yap; Eric D Bloch
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2.  Temperature-regulated guest admission and release in microporous materials.

Authors:  Gang Kevin Li; Jin Shang; Qinfen Gu; Rohan V Awati; Nathan Jensen; Andrew Grant; Xueying Zhang; David S Sholl; Jefferson Z Liu; Paul A Webley; Eric F May
Journal:  Nat Commun       Date:  2017-06-09       Impact factor: 14.919

3.  Enhancing the stability and porosity of penetrated metal-organic frameworks through the insertion of coordination sites.

Authors:  Rui Feng; Yan-Yuan Jia; Zhao-Yang Li; Ze Chang; Xian-He Bu
Journal:  Chem Sci       Date:  2017-11-15       Impact factor: 9.825

4.  Four 3D coordination polymers based on layers with single syn-anti carboxylate bridges: synthesis, structures, and magnetic properties.

Authors:  Wei Gao; Feng Liu; Xiu-Mei Zhang; Jie-Ping Liu; Qing-Yu Gao
Journal:  RSC Adv       Date:  2018-04-16       Impact factor: 4.036

5.  Strongly visible light-absorbing metal-organic frameworks functionalized by cyclometalated ruthenium(ii) complexes.

Authors:  Eirik Mydske Thoresen; Sigurd Øien-Ødegaard; Gurpreet Kaur; Mats Tilset; Karl Petter Lillerud; Mohamed Amedjkouh
Journal:  RSC Adv       Date:  2020-03-02       Impact factor: 4.036

6.  Metal/Carboxylate-Induced Versatile Structures of Nine 0D → 3D Complexes with Different Fluorescent and Electrochemical Behaviors.

Authors:  Guo-Cheng Liu; Xue Lu; Xiao-Wu Li; Xiu-Li Wang; Na Xu; Yan Li; Hong-Yan Lin; Yong-Qiang Chen
Journal:  ACS Omega       Date:  2019-10-08
  6 in total

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