Literature DB >> 27782352

Mild and Selective Cobalt-Catalyzed Chemodivergent Transfer Hydrogenation of Nitriles.

Zhihui Shao1,2, Shaomin Fu1, Mufeng Wei1, Shaolin Zhou2, Qiang Liu1.   

Abstract

Herein, we describe a selective cobalt-catalyzed chemodivergent transfer hydrogenation of nitriles to synthesize primary, secondary, and tertiary amines. The solvent effect plays a key role for the selectivity control. The general applicability of this procedure was highlighted by the synthesis of more than 70 amine products bearing various functional groups in high chemoselectivity. Moreover, this mild system achieved >2000 TONs (turnover numbers) for the transfer hydrogenation of nitriles.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  amines; cobalt; nitriles; reductive amination; transfer hydrogenation

Year:  2016        PMID： 27782352     DOI： 10.1002/anie.201608345

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines.

Authors:  Pandula T Kirinde Arachchige; Hanbin Lee; Chae S Yi
Journal:  J Org Chem       Date:  2018-04-24       Impact factor: 4.354

2.  Alkene Metalates as Hydrogenation Catalysts.

Authors:  Philipp Büschelberger; Dominik Gärtner; Efrain Reyes-Rodriguez; Friedrich Kreyenschmidt; Konrad Koszinowski; Axel Jacobi von Wangelin; Robert Wolf
Journal:  Chemistry       Date:  2017-02-06       Impact factor: 5.236

3.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

4.  Synthesis and reactivity of a PCcarbeneP cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N).

Authors:  Simon Sung; Qingyang Wang; Tobias Krämer; Rowan D Young
Journal:  Chem Sci       Date:  2018-09-06       Impact factor: 9.825

5.  Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2-Propanol and 1,4-Butanediol as the Hydrogen Source.

Authors:  Jorge A Garduño; Juventino J García
Journal:  ACS Omega       Date:  2017-05-26

6.  Computational Prediction of Ammonia-Borane Dehydrocoupling and Transfer Hydrogenation of Ketones and Imines Catalyzed by SCS Nickel Pincer Complexes.

Authors:  Bing Qiu; Wan Wang; Xinzheng Yang
Journal:  Front Chem       Date:  2019-09-13       Impact factor: 5.221

7.  General Construction of Amine via Reduction of N=X (X = C, O, H) Bonds Mediated by Supported Nickel Boride Nanoclusters.

Authors:  Da Ke; Shaodong Zhou
Journal:  Int J Mol Sci       Date:  2022-08-19       Impact factor: 6.208

8.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

9.  Pd-CuFe Catalyst for Transfer Hydrogenation of Nitriles: Controllable Selectivity to Primary Amines and Secondary Amines.

Authors:  Lei Liu; Yuhong Liu; Yongjian Ai; Jifan Li; Junjie Zhou; Zhibo Fan; Hongjie Bao; Ruihang Jiang; Zenan Hu; Jingting Wang; Ke Jing; Yue Wang; Qionglin Liang; Hongbin Sun
Journal:  iScience       Date:  2018-09-19

10.  Transfer Hydrogenation of Ketones Catalyzed by Symmetric Imino-N-heterocyclic Carbene Co(III) Complexes.

Authors:  Samaila Abubakar; Muhammad D Bala
Journal:  ACS Omega       Date:  2020-02-06
  10 in total

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