| Literature DB >> 27779269 |
Yao Liu1, Chu-Jun Zhou1, Qingjiang Li2, Honggen Wang1.
Abstract
The first total synthesis of structurally unique polycyclic phenolic meroterpenoids, ganocins B and C is reported. The synthesis features gold-catalyzed intramolecular cascade cyclization to construct the C/D ring bearing an angular methyl group, diastereoselective Michael addition, and acid-mediated one-pot Robinson cyclization/deprotection/isomerization.Entities:
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Year: 2016 PMID: 27779269 DOI: 10.1039/c6ob02049f
Source DB: PubMed Journal: Org Biomol Chem ISSN: 1477-0520 Impact factor: 3.876