Literature DB >> 27774541

Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling.

Audrey Beillard1, Xavier Bantreil, Thomas-Xavier Métro, Jean Martinez, Frédéric Lamaty.   

Abstract

A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.

Entities:  

Year:  2016        PMID： 27774541     DOI： 10.1039/c6dt03564g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Critical Assessment of the Reducing Ability of Breslow-type Derivatives and Implications for Carbene-Catalyzed Radical Reactions*.

Authors:  Ludivine Delfau; Samantha Nichilo; Florian Molton; Julie Broggi; Eder Tomás-Mendivil; David Martin
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-15       Impact factor: 16.823

2.  Coinage Metal Complexes of the Carbenic Tautomer of a Conjugated Mesomeric Betaine Akin to Nitron.

Authors:  Charlotte Thie; Clemens Bruhn; Michael Leibold; Ulrich Siemeling
Journal:  Molecules       Date:  2017-07-07       Impact factor: 4.411
  2 in total

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