Literature DB >> 27774535

A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate.

Yan Duan1, Juan M Clemente-Juan1, José L G Fierro2, Carlos Giménez-Saiz1, Eugenio Coronado1.   

Abstract

Partial reductive hydrolysis of a penta-CoII/III cluster [Co(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

Entities:  

Year:  2016        PMID： 27774535     DOI： 10.1039/c6cc05485d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Tellurite-Squarate Driven Assembly of a New Family of Nanoscale Clusters Based on (Mo2 O2 S2 )2.

Authors:  Jamie W Purcell; Haralampos N Miras; De-Liang Long; Panagiota Markopoulou; Leroy Cronin
Journal:  Chemistry       Date:  2017-06-29       Impact factor: 5.236

2.  Large Magnetic Polyoxometalates Containing the Cobalt Cubane '[CoIIICo 3II (OH)3(H2O)6-m(PW9O34)]3-' (m = 3 or 5) as a Subunit.

Authors:  Yan Duan; Juan M Clemente-Juan; Carlos Giménez-Saiz; Eugenio Coronado
Journal:  Front Chem       Date:  2018-06-19       Impact factor: 5.221
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.