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Literature DB >> 27757466

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.

Rong-Jia Wei¹, Ryohei Nakahara¹, Jamie M Cameron¹, Graham N Newton², Takuya Shiga¹, Hajime Sagayama³, Reiji Kumai³, Youichi Murakami³, Hiroki Oshio¹.

Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Entities: Chemical

Year: 2016 PMID： 27757466 DOI： 10.1039/c6dt03416k

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

1 in total

1. Chameleonic layered metal-organic frameworks with variable charge-ordered states triggered by temperature and guest molecules.

Authors: Jian Chen; Yoshihiro Sekine; Atsushi Okazawa; Hiroyasu Sato; Wataru Kosaka; Hitoshi Miyasaka
Journal: Chem Sci Date: 2020-03-05 Impact factor: 9.825

1 in total