Literature DB >> 27739642

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex.

Guoqi Zhang1, Haisu Zeng2,3, Jing Wu2,3, Zhiwei Yin2,3, Shengping Zheng4, James C Fettinger5.   

Abstract

Well-defined manganese complexes based on inexpensive, readily available ligands, 2,2':6',2''-terpyridine and its derivatives have been prepared and employed for the selective hydroboration of alkenes, ketones and aldehydes. Highly Markovnikov regioselective hydroboration of styrenes as well as excellent chemoselective hydroboration of ketones over alkenes were achieved, for the first time, by an earth-abundant manganese catalyst.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Markovnikov selectivity; alkenes; carbonyl compounds; hydroboration; manganese catalysis

Year:  2016        PMID： 27739642     DOI： 10.1002/anie.201607579

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Earth-Abundant Transition Metal Catalysts for Alkene Hydrosilylation and Hydroboration: Opportunities and Assessments.

Authors:  Jennifer V Obligacion; Paul J Chirik
Journal:  Nat Rev Chem       Date:  2018-04-27       Impact factor: 34.035

2.  Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes.

Authors:  Guoqi Zhang; Sihan Li; Haisu Zeng; Shengping Zheng; Michelle C Neary
Journal:  RSC Adv       Date:  2022-06-29       Impact factor: 4.036

3.  Catalytic Hydroboration of Aldehydes, Ketones, and Alkenes Using Potassium Carbonate: A Small Key to Big Transformation.

Authors:  Da Hun Ma; Ashok Kumar Jaladi; Ji Hye Lee; Tae Sung Kim; Won Kyu Shin; Hyonseok Hwang; Duk Keun An
Journal:  ACS Omega       Date:  2019-09-20

4.  Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones.

Authors:  Xiaochen Ma; Ziqing Zuo; Guixia Liu; Zheng Huang
Journal:  ACS Omega       Date:  2017-08-18

5.  Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water.

Authors:  Ming Yang; Yunzi Yu; Wenxia Ma; Yuqin Feng; Gang Zhang; Yaqi Wu; Fanyu Zhou; Yongsheng Yang; Dezheng Liu
Journal:  RSC Adv       Date:  2022-03-29       Impact factor: 3.361

6.  Alkene hydroboration with pinacolborane catalysed by lithium diisobutyl-tert-butoxyaluminum hydride.

Authors:  Ashok Kumar Jaladi; Won Kyu Shin; Duk Keun An
Journal:  RSC Adv       Date:  2019-08-23       Impact factor: 3.361

7.  Manganese Alkyl Carbonyl Complexes: From Iconic Stoichiometric Textbook Reactions to Catalytic Applications.

Authors:  Stefan Weber; Karl Kirchner
Journal:  Acc Chem Res       Date:  2022-09-08       Impact factor: 24.466

8.  Markovnikov alcohols via epoxide hydroboration by molecular alkali metal catalysts.

Authors:  Guoqi Zhang; Haisu Zeng; Shengping Zheng; Michelle C Neary; Pavel A Dub
Journal:  iScience       Date:  2022-09-12

9.  A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight.

Authors:  Tufan K Mukhopadhyay; Marco Flores; Thomas L Groy; Ryan J Trovitch
Journal:  Chem Sci       Date:  2018-08-15       Impact factor: 9.825

10.  Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups.

Authors:  Christina Erken; Akash Kaithal; Suman Sen; Thomas Weyhermüller; Markus Hölscher; Christophe Werlé; Walter Leitner
Journal:  Nat Commun       Date:  2018-10-30       Impact factor: 14.919
  10 in total

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