Literature DB >> 27734527

Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand.

Felix Schneck1, Markus Finger1, Moniek Tromp2, Sven Schneider1.   

Abstract

The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2 )2 }] is reported. This compound exhibits reversible, ligand-centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C-H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; hydrogen atom transfer; nickel; non-innocent ligands; pincer ligands

Year:  2016        PMID： 27734527     DOI： 10.1002/chem.201604407

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  10 in total

1.  Reversible nickel-metallacycle formation with a phosphinimine-based pincer ligand.

Authors:  Xiujing Xing; Shaoguang Zhang; Laura M Thierer; Michael R Gau; Patrick J Carroll; Neil C Tomson
Journal:  Dalton Trans       Date:  2020-05-27       Impact factor: 4.390

2.  Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand.

Authors:  Kate A Jesse; Mu-Chieh Chang; Alexander S Filatov; John S Anderson
Journal:  Z Anorg Allg Chem       Date:  2021-05-27       Impact factor: 1.414

3.  Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands.

Authors:  V Mahesh Krishnan; Ian Davis; Tessa M Baker; Daniel J Curran; Hadi D Arman; Michael L Neidig; Aimin Liu; Zachary J Tonzetich
Journal:  Inorg Chem       Date:  2018-07-24       Impact factor: 5.165

4.  Catalytic hydrogenation enabled by ligand-based storage of hydrogen.

Authors:  Andrew J McNeece; Kate A Jesse; Alexander S Filatov; Joseph E Schneider; John S Anderson
Journal:  Chem Commun (Camb)       Date:  2021-03-17       Impact factor: 6.222

5.  The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion.

Authors:  Felix Schneck; Jennifer Ahrens; Markus Finger; A Claudia Stückl; Christian Würtele; Dirk Schwarzer; Sven Schneider
Journal:  Nat Commun       Date:  2018-03-21       Impact factor: 14.919

6.  Roles of Hydrogen Bonding in Proton Transfer to κP,κN,κP-N(CH2CH2P i Pr2)2-Ligated Nickel Pincer Complexes.

Authors:  Nadeesha P N Wellala; John D Luebking; Jeanette A Krause; Hairong Guan
Journal:  ACS Omega       Date:  2018-05-08

7.  Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes.

Authors:  Cody B van Beek; Nicolaas P van Leest; Martin Lutz; Sander D de Vos; Robertus J M Klein Gebbink; Bas de Bruin; Daniël L J Broere
Journal:  Chem Sci       Date:  2022-01-18       Impact factor: 9.825

8.  Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen.

Authors:  Sophie W Anferov; Alexander S Filatov; John S Anderson
Journal:  ACS Catal       Date:  2022-08-01       Impact factor: 13.700

9.  Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

Authors:  Jarl Ivar van der Vlugt
Journal:  Chemistry       Date:  2018-11-26       Impact factor: 5.236

10.  Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere.

Authors:  Kate A Jesse; Sophie W Anferov; Kelsey A Collins; Juan A Valdez-Moreira; Maia E Czaikowski; Alexander S Filatov; John S Anderson
Journal:  J Am Chem Soc       Date:  2021-10-26       Impact factor: 15.419
  10 in total

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