Literature DB >> 27731915

Ru-Catalyzed Dehydrogenative C-O Bond Formation with Anilines and Phenols.

Christophe Heitz1, Alexander W Jones1, Bünyamin S Oezkaya1, Christina L Bub1, Marie-Laure Louillat-Habermeyer1, Victoria Wagner1, Frederic W Patureau1.   

Abstract

The Ru catalyzed cross-dehydrogenative C-O bond formation between anilines and phenols is described and discussed. The exclusive C-O versus C-N bond-formation selectivity, moreover in the absence of chelating-assisting directing groups and while leaving the N-H position untouched, is a remarkable feature of this metal-catalyzed radical cross-dehydrogenative coupling.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; C−O bond formation; aniline; cross-dehydrogenative couplings; ruthenium

Year:  2016        PMID： 27731915     DOI： 10.1002/chem.201604764

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  3 in total

1.  Cross dehydrogenative C-O coupling catalysed by a catenane-coordinated copper(i).

Authors:  Lihui Zhu; Jiasheng Li; Jun Yang; Ho Yu Au-Yeung
Journal:  Chem Sci       Date:  2020-11-01       Impact factor: 9.825

2.  Mechanism of the Dehydrogenative Phenothiazination of Phenols.

Authors:  Monalisa Goswami; Alexander Konkel; Maryam Rahimi; Marie-Laure Louillat-Habermeyer; Harald Kelm; Rongwei Jin; Bas de Bruin; Frederic W Patureau
Journal:  Chemistry       Date:  2018-07-25       Impact factor: 5.236

3.  Cu-Catalyzed Cross-Dehydrogenative ortho-Aminomethylation of Phenols.

Authors:  Congjun Yu; Frederic W Patureau
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-01       Impact factor: 15.336
  3 in total

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