| Literature DB >> 27722692 |
Xiaoqiang Zhou1, Haojie Ma1, Jinhui Cao1, Xingxing Liu1, Guosheng Huang1.
Abstract
Hydrogen peroxide and anhydride mediated transformation of enamides to afford substituted α-acyloxy ketones is described. This transition-metal-free cascade reaction has a broad substrate scope and high efficiency. The acyl intramolecular migration procedure successfully achieved this acyloxylation process under mild conditions and increased the atom efficiency.Entities:
Year: 2016 PMID： 27722692 DOI： 10.1039/c6ob02002j
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876