Literature DB >> 27722674

Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site.

Danny Schuhknecht1, Florian Ritter1, Michael E Tauchert1.   

Abstract

The palladium diphosphinoboryl pincer [{(o-PPh2C6H4)2B}PdIII] 8 was prepared from the diphosphinoborane complex 6a. The boryl functionality of the pincer displayed ambiphilic properties allowing: (1) coordination of Lewis basic pyridines to the boryl site and (2) access to palladium diphosphinoborane complex derivatives.

Entities:  

Year:  2016        PMID： 27722674     DOI： 10.1039/c6cc07079e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Cooperative C-H activation of pyridine by PBP complexes of Rh and Ir can lead to bridging 2-pyridyls with different connectivity to the B-M unit.

Authors:  Yihan Cao; Wei-Chun Shih; Nattamai Bhuvanesh; Jia Zhou; Oleg V Ozerov
Journal:  Chem Sci       Date:  2021-10-05       Impact factor: 9.969

2.  Reversible addition of ethylene to a pincer-based boryl-iridium unit with the formation of a bridging ethylidene.

Authors:  Yihan Cao; Wei-Chun Shih; Nattamai Bhuvanesh; Oleg V Ozerov
Journal:  Chem Sci       Date:  2020-10-05       Impact factor: 9.825
  2 in total

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