Literature DB >> 27722639

Supramolecular 3d-4f single-molecule magnet architectures.

Sebastian Schmitz1, Jan van Leusen1, Natalya V Izarova2, Yanhua Lan3, Wolfgang Wernsdorfer4, Paul Kögerler5, Kirill Yu Monakhov1.   

Abstract

The nanosized self-assemblies {[{LnIII}{H2O⊂CrLn}]2(H2O)} (Ln = Dy, 1 and Tb, 2) based on new 3d-4f mixed-metal coordination topologies are formed via extensive intramolecular hydrogen bonding that is directed by enclosed water molecules. Compounds 1 and 2 show single-molecule magnet characteristics manifested by hysteresis loops up to 1.6 K (Ueff = 8.3 cm-1) and 1 K (Ueff = 3.4 cm-1), respectively.

Entities:  

Year:  2016        PMID: 27722639     DOI: 10.1039/c6dt03392j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  4 in total

1.  Heterometallic ZnII⁻LnIII⁻ZnII Schiff Base Complexes with Linear or Bent Conformation-Synthesis, Crystal Structures, Luminescent and Magnetic Characterization.

Authors:  Barbara Miroslaw; Beata Cristóvão; Zbigniew Hnatejko
Journal:  Molecules       Date:  2018-07-18       Impact factor: 4.411

2.  A new family of decanuclear Ln7Cr3 clusters exhibiting a magnetocaloric effect.

Authors:  Jia-Jia Yin; Tian-Qi Lu; Cheng Chen; Hai-Yan Shi; Gui-Lin Zhuang; Jun Zheng; Xiaolong Fang; Xiu-Ying Zheng
Journal:  RSC Adv       Date:  2021-05-12       Impact factor: 4.036

3.  Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr4Ln4} clusters stabilized by phthalic acid and [SiW12O40]4.

Authors:  Ya-Nan Gu; Dan Zhao; Hao Yu; Rui Ge; Zhong Li; Chong-Bian Tian; Xin-Xiong Li; Yan-Qiong Sun; Shou-Tian Zheng
Journal:  RSC Adv       Date:  2019-05-01       Impact factor: 3.361

4.  Conductive Self-Assembled Monolayers of Paramagnetic {CoII Co 4 III } and { Co 4 II Co 2 III } Coordination Clusters on Gold Surfaces.

Authors:  Sebastian Schmitz; Xinkai Qiu; Maria Glöß; Jan van Leusen; Natalya V Izarova; Muhammad Arif Nadeem; Jan Griebel; Ryan C Chiechi; Paul Kögerler; Kirill Yu Monakhov
Journal:  Front Chem       Date:  2019-11-05       Impact factor: 5.221

  4 in total

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