| Literature DB >> 27722639 |
Sebastian Schmitz1, Jan van Leusen1, Natalya V Izarova2, Yanhua Lan3, Wolfgang Wernsdorfer4, Paul Kögerler5, Kirill Yu Monakhov1.
Abstract
The nanosized self-assemblies {[{LnIII}{H2O⊂CrLn}]2(H2O)} (Ln = Dy, 1 and Tb, 2) based on new 3d-4f mixed-metal coordination topologies are formed via extensive intramolecular hydrogen bonding that is directed by enclosed water molecules. Compounds 1 and 2 show single-molecule magnet characteristics manifested by hysteresis loops up to 1.6 K (Ueff = 8.3 cm-1) and 1 K (Ueff = 3.4 cm-1), respectively.Entities:
Year: 2016 PMID: 27722639 DOI: 10.1039/c6dt03392j
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390