| Literature DB >> 27722523 |
Suzanne E Witt1, Travis A White1, Zhanyong Li2, Kim R Dunbar2, Claudia Turro1.
Abstract
Two formamidinate bridged dirhodium(ii,ii) complexes with chelating diimine ligands L, [Rh2(μ-DTolF)2(L)2]2+, were shown to electrocatalytically reduce CO2 in the presence of H2O. Analysis of the reaction mixture and headspace following bulk electrolysis revealed H2 and HCOOH as the major products. The variation in relative product formation is discussed.Entities:
Year: 2016 PMID： 27722523 DOI： 10.1039/c6cc03253b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222