Literature DB >> 27722255

An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.

Vianney Regnier1, Florian Molton1, Christian Philouze1, David Martin1.   

Abstract

We report an experimental and theoretical study of the 1,1,3,3-tetrakis-di(methylamino)oxyallyl radical cation. Despite simple substituents with minimal steric hindrance, this radical was found to be stable under an inert atmosphere and persistent for several hours in well-aerated solutions.

Entities:  

Year:  2016        PMID： 27722255     DOI： 10.1039/c6cc06260a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5-Aminothiazoles.

Authors:  Kirara Yamaguchi; Toshiaki Murai; Shoichi Kutsumizu; Yohei Miwa; Masahiro Ebihara; Jing-Dong Guo; Norihiro Tokitoh
Journal:  ChemistryOpen       Date:  2017-03-15       Impact factor: 2.911

2.  Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands.

Authors:  Monika Tripathi; Vianney Regnier; Zakaria Ziani; Marc Devillard; Christian Philouze; David Martin
Journal:  RSC Adv       Date:  2018-11-14       Impact factor: 3.361

3.  The curious case of a sterically crowded Stenhouse salt.

Authors:  Valentin Théry; Florian Molton; Selim Sirach; Neven Tillet; Jacques Pécaut; Eder Tomás-Mendivil; David Martin
Journal:  Chem Sci       Date:  2022-07-27       Impact factor: 9.969

4.  Synthesis of Fluorogenic Arylureas and Amides and Their Interaction with Amines: A Competition between Turn-on Fluorescence and Organic Radicals on the Way to a Smart Label for Fish Freshness.

Authors:  Javier García-Tojal; José V Cuevas; María-Josefa Rojo; Borja Díaz de Greñu; Carla Hernando-Muñoz; José García-Calvo; Mateo M Salgado; Tomás Torroba
Journal:  Molecules       Date:  2021-03-05       Impact factor: 4.411
  4 in total

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