| Literature DB >> 27722247 |
Antonio Santoru1, Claudio Pistidda2, Magnus H Sørby3, Michele R Chierotti4, Sebastiano Garroni5, Eugenio Pinatel4, Fahim Karimi2, Hujun Cao2, Nils Bergemann2, Thi T Le2, Julián Puszkiel6, Roberto Gobetto4, Marcello Baricco4, Bjørn C Hauback3, Thomas Klassen2, Martin Dornheim2.
Abstract
We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2- ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.Entities:
Year: 2016 PMID： 27722247 DOI： 10.1039/c6cc05777b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222