Literature DB >> 27714548

Microwave Assisted Synthesis, Optical Properties and Physicochemical Investigations on the Powerful Fluorophore: Donor (D) -π-Acceptor (A) Chalcone.

Salman A Khan1, Abdullah M Asiri2,3, Faisal M S Aqlan2.   

Abstract

(2E)-3-[4-(dimethylamino)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one (DPHP) was synthesized by the reaction 4(dimethylamino) benzaldehyde with 1-(2-hydroxyphenyl) ethanone under microwave irradiation. Structure of DPHP was conformed by 1H and 13C NMR, FT-IR, EI-MS spectral studies and elemental analysis. The electronic absorption and fluorescence spectra of DPHP have been studied in solvents of different polarities, and the data were used to study the solvatochromic properties such as extinction coefficient, stokes shift, oscillator strength, transition dipole moment, fluorescence quantum yield and photochemical quantum yield. The absorption maximum and fluorescence emission maximum was observed red shift when increase solvent polarity n-Hexane to DMF. DPHP undergoes solubilization in different micelles and may be used as a probe and quencher to determine the critical micelle concentration (CMC) of CTAB and SDS.

Entities:  

Keywords:  CMC; DPHP; Fluorescence quantum yield; Photochemical quantum yield; Solvatochromic

Year:  2016        PMID: 27714548     DOI: 10.1007/s10895-016-1909-x

Source DB:  PubMed          Journal:  J Fluoresc        ISSN: 1053-0509            Impact factor:   2.217


  13 in total

1.  Synthesis of some novel chalcones, flavanones and flavones and evaluation of their anti-inflammatory activity.

Authors:  Sameena Bano; Kalim Javed; Shamim Ahmad; I G Rathish; Surender Singh; M Chaitanya; K M Arunasree; M S Alam
Journal:  Eur J Med Chem       Date:  2013-05-03       Impact factor: 6.514

2.  Solvent effect on the relative quantum yield and fluorescence quenching of 2DAM.

Authors:  D Nagaraja; R M Melavanki; N R Patil; R A Kusanur
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2014-03-31       Impact factor: 4.098

3.  New insights into the solvent-assisted excited-state double proton transfer of 2-(1H-pyrazol-5-yl)pyridine with alcoholic partners: a TDDFT investigation.

Authors:  Hui Li; Ying Shi; Hang Yin; Ye Wang; Lin Cong; Mingxing Jin; Dajun Ding
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2015-01-31       Impact factor: 4.098

4.  Changes in energy of three types of hydrogen bonds upon excitation of aminocoumarins determined from absorption solvatochromic experiments.

Authors:  Ewa Krystkowiak; Andrzej Maciejewski
Journal:  Phys Chem Chem Phys       Date:  2011-05-13       Impact factor: 3.676

Review 5.  Recent developments in biological activities of chalcones: a mini review.

Authors:  Parvesh Singh; Amit Anand; Vipan Kumar
Journal:  Eur J Med Chem       Date:  2014-08-12       Impact factor: 6.514

6.  Thermal solvent-free synthesis of novel pyrazolyl chalcones and pyrazolines as potential antimicrobial agents.

Authors:  Zeba N Siddiqui; T N Mohammed Musthafa; Anis Ahmad; Asad U Khan
Journal:  Bioorg Med Chem Lett       Date:  2011-03-30       Impact factor: 2.823

7.  Evaluation of dihydroquercetin-3-O-glucoside from Malbec grapes as copigment of malvidin-3-O-glucoside.

Authors:  Martín Fanzone; Susana González-Manzano; Joaquín Pérez-Alonso; María Teresa Escribano-Bailón; Viviana Jofré; Mariela Assof; Celestino Santos-Buelga
Journal:  Food Chem       Date:  2014-11-27       Impact factor: 7.514

8.  Donor-acceptor substituted phenylethynyltriphenylenes - excited state intramolecular charge transfer, solvatochromic absorption and fluorescence emission.

Authors:  Ritesh Nandy; Sethuraman Sankararaman
Journal:  Beilstein J Org Chem       Date:  2010-10-18       Impact factor: 2.883

9.  Nonparallel Stacks of Donor and Acceptor Chromophores Evade Geminate Charge Recombination.

Authors:  Ajith R Mallia; P S Salini; Mahesh Hariharan
Journal:  J Am Chem Soc       Date:  2015-10-14       Impact factor: 15.419

10.  Unusually high fluorescence quantum yield of a homopolyfluorenylazomethine--towards a universal fluorophore.

Authors:  Charlotte Mallet; Andréanne Bolduc; Sophie Bishop; Yohan Gautier; W G Skene
Journal:  Phys Chem Chem Phys       Date:  2014-11-28       Impact factor: 3.676

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  1 in total

1.  Investigation of Solvent Effects on Photophysical Properties of New Aminophthalimide Derivatives-Based on Methanesulfonate.

Authors:  Ayse Tan; Ebru Bozkurt; Yunus Kara
Journal:  J Fluoresc       Date:  2017-01-11       Impact factor: 2.217

  1 in total

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