Literature DB >> 27711330

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb).

Flavia Pop1, Pascale Auban-Senzier2, Enric Canadell3, Narcis Avarvari1.   

Abstract

Control of the structural type in metallic enantiopure and racemic radical cation salts is achieved through hydrogen bonding interactions between the chiral donor DM-EDT-TTF and the XF6 anions (X = P, As, Sb), determined by the anion size and the chiral information.

Entities:  

Year:  2016        PMID： 27711330     DOI： 10.1039/c6cc06706a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDT-TTF with the oxo-bis[pentafluorotantalate(v)] dianion.

Authors:  Nabil Mroweh; Cécile Mézière; Magali Allain; Pascale Auban-Senzier; Enric Canadell; Narcis Avarvari
Journal:  Chem Sci       Date:  2020-08-13       Impact factor: 9.825
  1 in total

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