Literature DB >> 27711298

Visible-light-mediated generation of nitrile oxides for the photoredox synthesis of isoxazolines and isoxazoles.

Thomas D Svejstrup1, Wojciech Zawodny1, James J Douglas2, Damon Bidgeli1, Nadeem S Sheikh3, Daniele Leonori1.   

Abstract

Visible-light photoredox catalysis enables the synthesis of biologically relevant isoxazolines and isoxazoles from hydroxyimino acids. The process shows broad functional group compatibility and mechanistic and computational studies support a visible-light-mediated generation of nitrile oxides by two sequential oxidative single electron transfer processes.

Entities:  

Year:  2016        PMID： 27711298     DOI： 10.1039/c6cc06029c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  An Electrochemical Way to Generate Amphiphiles from Hydrazones for the Synthesis of 1,2,4-Triazole Scaffold Cyclic Compounds.

Authors:  Wangyu Li; Mingteng Xiong; Xiao Liang; Dungai Wang; Heping Zhu; Yuanjiang Pan
Journal:  ChemistryOpen       Date:  2022-01       Impact factor: 2.911

2.  Electrochemical Synthesis of Isoxazolines: Method and Mechanism.

Authors:  Samuel D L Holman; Alfie G Wills; Neal J Fazakerley; Darren L Poole; Diane M Coe; Leonard A Berlouis; Marc Reid
Journal:  Chemistry       Date:  2022-02-10       Impact factor: 5.020

3.  [2 + 2 + 1] Cycloaddition of N-tosylhydrazones, tert-butyl nitrite and alkenes: a general and practical access to isoxazolines.

Authors:  Liang Ma; Feng Jin; Xionglve Cheng; Suyan Tao; Gangzhong Jiang; Xingxing Li; Jinwei Yang; Xiaoguang Bao; Xiaobing Wan
Journal:  Chem Sci       Date:  2021-06-22       Impact factor: 9.825
  3 in total

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