| Literature DB >> 27709151 |
RahulKumar Rajmani Singh1, Samir Kundlik Pawar1, Min-Jie Huang1, Rai-Shung Liu1.
Abstract
Gold-catalyzed [3+2]-annulations of α-aryl diazonitriles with ynamides and allenamides yield 1-amino-1H-indenes in two distinct pathways; the success of these annulations relies on the high electrophilicity of α-cyano arylgold carbenes to activate an ionic pathway.Entities:
Year: 2016 PMID： 27709151 DOI： 10.1039/c6cc04308a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222