Literature DB >> 27700073

Iterative Synthesis of Oligo[n]rotaxanes in Excellent Yield.

James E M Lewis1, Joby Winn2, Luca Cera2, Stephen M Goldup1.   

Abstract

We present an operationally simple iterative coupling strategy for the synthesis of oligomeric homo- and hetero[n]rotaxanes with precise control over the position of each macrocycle. The exceptional yield of the AT-CuAAC reaction, combined with optimized conditions that allow the rapid synthesis of the target oligomers, opens the door to the study of precision-engineered oligomeric interlocked molecules.

Entities:  

Year:  2016        PMID： 27700073     DOI： 10.1021/jacs.6b08958

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  22 in total

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4.  One-pot synthesis of hetero[6]rotaxane bearing three different kinds of macrocycle through a self-sorting process.

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7.  Porphyrinoid rotaxanes: building a mechanical picket fence.

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8.  Efficient Multicomponent Active Template Synthesis of Catenanes.

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9.  A Fluorescent Ditopic Rotaxane Ion-Pair Host.

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10.  Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes.

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