Literature DB >> 27690396

Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py.

Dóra Lakk-Bogáth1, Róbert Csonka1, Gábor Speier1, Marius Réglier2, A Jalila Simaan2, Jean-Valère Naubron3, Michel Giorgi3, Károly Lázár4, József Kaizer1.   

Abstract

The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [FeIV(O)(asN4Py)]2+ (2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.

Entities:  

Year:  2016        PMID： 27690396     DOI： 10.1021/acs.inorgchem.6b01089

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported RuII complexes: comparison to bimetallic analogs.

Authors:  Sungho V Park; John F Berry
Journal:  Dalton Trans       Date:  2017-07-18       Impact factor: 4.390

2.  Comparison of Nonheme Manganese- and Iron-Containing Flavone Synthase Mimics.

Authors:  Dóra Lakk-Bogáth; Natalija Pantalon Juraj; Bashdar I Meena; Berislav Perić; Srećko I Kirin; József Kaizer
Journal:  Molecules       Date:  2021-05-27       Impact factor: 4.411

3.  Stability and Catalase-Like Activity of a Mononuclear Non-Heme Oxoiron(IV) Complex in Aqueous Solution.

Authors:  Balázs Kripli; Bernadett Sólyom; Gábor Speier; József Kaizer
Journal:  Molecules       Date:  2019-09-05       Impact factor: 4.411
  3 in total

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