Literature DB >> 27690363

Hydrogenation of Esters to Alcohols Catalyzed by Defined Manganese Pincer Complexes.

Saravanakumar Elangovan1, Marcel Garbe1, Haijun Jiao1, Anke Spannenberg1, Kathrin Junge1, Matthias Beller1.   

Abstract

The first manganese-catalyzed hydrogenation of esters to alcohols has been developed. The combination of Mn(CO)5 Br with [HN(CH2 CH2 P(Et)2 )2 ] leads to a mixture of cationic and neutral Mn PNP pincer complexes, which enable the reduction of various ester substrates, including aromatic and aliphatic esters as well as diesters and lactones. Notably, related pincer complexes with isopropyl or cyclohexyl substituents showed very low activity.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alcohols; esters; homogeneous catalysis; hydrogenation; manganese

Year:  2016        PMID： 27690363     DOI： 10.1002/anie.201607233

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  23 in total

1.  Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

Authors:  Kristian E Dalle; Julien Warnan; Jane J Leung; Bertrand Reuillard; Isabell S Karmel; Erwin Reisner
Journal:  Chem Rev       Date:  2019-02-15       Impact factor: 60.622

2.  Utilizing Design of Experiments Approach to Assess Kinetic Parameters for a Mn Homogeneous Hydrogenation Catalyst.

Authors:  Robin K A van Schendel; Wenjun Yang; Evgeny A Uslamin; Evgeny A Pidko
Journal:  ChemCatChem       Date:  2021-09-14       Impact factor: 5.497

3.  Basic Promotors Impact Thermodynamics and Catalyst Speciation in Homogeneous Carbonyl Hydrogenation.

Authors:  Wenjun Yang; Tejas Y Kalavalapalli; Annika M Krieger; Taras A Khvorost; Ivan Yu Chernyshov; Manuela Weber; Evgeny A Uslamin; Evgeny A Pidko; Georgy A Filonenko
Journal:  J Am Chem Soc       Date:  2022-04-27       Impact factor: 16.383

4.  Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions.

Authors:  Stefan Weber; Julian Brünig; Luis F Veiros; Karl Kirchner
Journal:  Organometallics       Date:  2021-04-22       Impact factor: 3.876

5.  CH2 Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors:  Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal:  Sci Rep       Date:  2017-06-21       Impact factor: 4.379

6.  Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

Authors:  Robbert van Putten; Evgeny A Uslamin; Marcel Garbe; Chong Liu; Angela Gonzalez-de-Castro; Martin Lutz; Kathrin Junge; Emiel J M Hensen; Matthias Beller; Laurent Lefort; Evgeny A Pidko
Journal:  Angew Chem Int Ed Engl       Date:  2017-04-21       Impact factor: 15.336

7.  A Manganese Nanosheet: New Cluster Topology and Catalysis.

Authors:  Uttam Chakraborty; Efrain Reyes-Rodriguez; Serhiy Demeshko; Franc Meyer; Axel Jacobi von Wangelin
Journal:  Angew Chem Int Ed Engl       Date:  2018-03-23       Impact factor: 15.336

8.  Carbon monoxide and hydrogen (syngas) as a C1-building block for selective catalytic methylation.

Authors:  Akash Kaithal; Markus Hölscher; Walter Leitner
Journal:  Chem Sci       Date:  2020-11-20       Impact factor: 9.825

9.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

10.  How Solvent Affects C-H Activation and Hydrogen Production Pathways in Homogeneous Ru-Catalyzed Methanol Dehydrogenation Reactions.

Authors:  Vivek Sinha; Nitish Govindarajan; Bas de Bruin; Evert Jan Meijer
Journal:  ACS Catal       Date:  2018-06-12       Impact factor: 13.084
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