Literature DB >> 27690249

Chiral Phosphoric Acid Catalyzed Asymmetric Oxidative Dearomatization of Naphthols with Quinones.

Gongming Zhu1,2, Guangjun Bao2, Yiping Li2, Junxian Yang2, Wangsheng Sun2, Jing Li1,2, Liang Hong1, Rui Wang1,2.   

Abstract

A highly enantioselective oxidative dearomatization of naphthols with quinones catalyzed by a chiral spirocyclic phosphoric acid is described. The strategy provides concise access to enantioenriched cyclohexadienones with a quinone moiety. Remarkably, the obtained products could be easily transformed to a potentially useful dihydronaphtho[2,1-b]benzofuran scaffold.

Entities:  

Year:  2016        PMID: 27690249     DOI: 10.1021/acs.orglett.6b02609

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Chiral phosphoric acid catalyzed aminative dearomatization of α-naphthols/Michael addition sequence.

Authors:  Zi-Lei Xia; Chao Zheng; Ren-Qi Xu; Shu-Li You
Journal:  Nat Commun       Date:  2019-07-17       Impact factor: 14.919

2.  Selective skeletal editing of polycyclic arenes using organophotoredox dearomative functionalization.

Authors:  Peng Ji; Cassondra C Davies; Feng Gao; Jing Chen; Xiang Meng; Kendall N Houk; Shuming Chen; Wei Wang
Journal:  Nat Commun       Date:  2022-08-05       Impact factor: 17.694

3.  2-Methoxyhydroquinone from Vanillin for Aqueous Redox-Flow Batteries.

Authors:  Werner Schlemmer; Philipp Nothdurft; Alina Petzold; Gisbert Riess; Philipp Frühwirt; Max Schmallegger; Georg Gescheidt-Demner; Roland Fischer; Stefan A Freunberger; Wolfgang Kern; Stefan Spirk
Journal:  Angew Chem Int Ed Engl       Date:  2020-10-08       Impact factor: 15.336

  3 in total

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