Literature DB >> 27670263

Water-in-Supercritical CO2 Microemulsion Stabilized by a Metal Complex.

Tian Luo1, Jianling Zhang2, Xiuniang Tan1, Chengcheng Liu1, Tianbin Wu1, Wei Li1, Xinxin Sang1, Buxing Han1, Zhihong Li1, Guang Mo1, Xueqing Xing1, Zhonghua Wu1.   

Abstract

Herein we propose for the first time the utilization of a metal complex for forming water-in-supercritical CO2 (scCO2 ) microemulsions. The water solubility in the metal-complex-stabilized microemulsion is significantly improved compared with the conventional water-in-scCO2 microemulsions stabilized by hydrocarbons. Such a microemulsion provides a promising route for the in situ CO2 reduction catalyzed by a metal complex at the water/scCO2 interface.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CO2 reduction; iron complexes; microemulsions; photocatalysis; supercritical CO2

Year:  2016        PMID： 27670263     DOI： 10.1002/anie.201608695

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  1 in total

1.  Cu x Ni y alloy nanoparticles embedded in a nitrogen-carbon network for efficient conversion of carbon dioxide.

Authors:  Dongxing Tan; Jianling Zhang; Xiuyan Cheng; Xiuniang Tan; Jinbiao Shi; Bingxing Zhang; Buxing Han; Lirong Zheng; Jing Zhang
Journal:  Chem Sci       Date:  2019-03-15       Impact factor: 9.825
  1 in total

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