Spectroscopic Properties of Phase-Pure and Polytypic Colloidal Semiconductor Quantum Wires.

We report ensemble extinction and photoluminesence spectra for colloidal CdTe quantum wires (QWs) with nearly phase-pure, defect-free wurtzite (WZ) structure, having spectral line widths comparable to the best ensemble or single quantum-dot values, to the single polytypic (having WZ and zinc blende (ZB) alternations) QW values, and to those of two-dimensional quantum belts or platelets. The electronic structures determined from the multifeatured extinction spectra are in excellent agreement with the theoretical results of WZ QWs having the same crystallographic orientation. Optical properties of polytypic QWs of like diameter and diameter distribution are provided for comparison, which exhibit smaller bandgaps and broader spectral line widths. The nonperiodic WZ-ZB alternations are found to generate non-negligible shifts of the bandgap to intermediate energies between the quantum-confined WZ and ZB energies. The alternations and variations in the domain sizes result in inhomogeneous spectral line width broadening that may be more significant than that arising from the 12-13% diameter distributions within the QW ensembles.