| Literature DB >> 27623023 |
Samantha A Green1, Jeishla L M Matos1, Akiko Yagi1, Ryan A Shenvi1.
Abstract
A combination of cobalt and nickel catalytic cycles enables a highly branch-selective (Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are consistent with hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a nickel cycle.Entities:
Year: 2016 PMID: 27623023 DOI: 10.1021/jacs.6b08507
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419