| Literature DB >> 27611111 |
Murali Mohan Guru1, Takanori Shima1,2, Zhaomin Hou3,4.
Abstract
Activation and functionalization of N2 : A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles. Functional groups such as aromatic C-X (X=Cl, Br, I) bonds, nitro groups, and ammonia-sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method.Entities:
Keywords: dinitrogen activation; hydrides; nitriles; organometallics; titanium
Year: 2016 PMID： 27611111 DOI： 10.1002/anie.201607426
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336