Literature DB >> 27596265

Nickel Catalysis Enables Oxidative C(sp(2) )-H/C(sp(2) )-H Cross-Coupling Reactions between Two Heteroarenes.

Yangyang Cheng1, Yimin Wu1, Guangyin Tan1, Jingsong You2.   

Abstract

Nickel can be used to promote oxidative C(sp(2) )-H/C(sp(2) )-H cross-coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional-group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  heteroarenes; homogeneous catalysis; nickel; oxidative cross-coupling; synthetic methods

Year:  2016        PMID： 27596265     DOI： 10.1002/anie.201606529

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  On the Nature of C(sp3)-C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides.

Authors:  Mingbin Yuan; Zhihui Song; Shorouk O Badir; Gary A Molander; Osvaldo Gutierrez
Journal:  J Am Chem Soc       Date:  2020-04-01       Impact factor: 15.419

2.  Rhodium-catalyzed ortho-heteroarylation of phenols: directing group-enabled switching of the electronic bias for heteroaromatic coupling partner.

Authors:  Yimin Wu; Wei Li; Linfeng Jiang; Luoqiang Zhang; Jingbo Lan; Jingsong You
Journal:  Chem Sci       Date:  2018-07-18       Impact factor: 9.825

3.  Ni(ii)-catalyzed mono-selective ortho-arylation of unactivated aryl C-H bonds utilizing amino acids as a directing group.

Authors:  Zhanqing Cong; Feng Gao; Hong Liu
Journal:  RSC Adv       Date:  2019-04-08       Impact factor: 4.036

4.  Green synthesis and crystal structure of 3-(benzo-thia-zol-2-yl)thio-phene.

Authors:  Linh Nguyen Ngoc; Trung Vu Quoc; Hoan Duong Quoc; Manh Vu Quoc; Luong Truong Minh; Chien Thang Pham; Luc Van Meervelt
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-10-13
  4 in total

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