Literature DB >> 27583399

Olefination of Electron-Deficient Alkenes with Allyl Acetate: Stereo- and Regioselective Access to (2Z,4E)-Dienamides.

Feifei Li1, Chunbing Yu1, Jian Zhang1, Guofu Zhong1.   

Abstract

A Ru-catalyzed direct olefination of electron-deficient alkenes with allyl acetate via C-H bond activation is disclosed. By using N,N-disubstituted aminocarbonyl as the directing group, this external oxidant-free protocol resulted in high reaction efficiency and good stereo- and regioselectivities, which opens a novel synthetic passway for access to (Z,E)-butadiene skeletons.

Entities:  

Year:  2016        PMID： 27583399     DOI： 10.1021/acs.orglett.6b02229

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate.

Authors:  Liyuan Ding; Chunbing Yu; Zhenqiang Zhao; Feifei Li; Jian Zhang; Guofu Zhong
Journal:  J Vis Exp       Date:  2017-06-21       Impact factor: 1.355

Review 2.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

3.  Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters.

Authors:  Bryce N Thomas; Patrick J Moon; Shengkang Yin; Alex Brown; Rylan J Lundgren
Journal:  Chem Sci       Date:  2017-10-24       Impact factor: 9.825
  3 in total

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