| Literature DB >> 27557755 |
Amélie Chabrier1, Alexandre Bruneau1, Sara Benmahdjoub2, Belkacem Benmerad2, Sabrina Belaid2, Jean-Daniel Brion1, Mouâd Alami1, Samir Messaoudi3.
Abstract
An efficient thioglycosylation of C(sp2 )-H bonds with thiosugars has been established for the first time. Using only Cu(OAc)2 ⋅H2 O as a catalyst and Ag2 CO3 as an additive in DMSO, the protocol proved to have broad scope, and a variety of complex thioglycosides have been prepared in good yields with exclusive β-selectivity.Entities:
Keywords: C−H bond activation; copper; homogeneous catalysis; thioglycosides; thioglycosylation reaction
Year: 2016 PMID： 27557755 DOI： 10.1002/chem.201602909
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236