Literature DB >> 27529617

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands.

Shogo Kuriyama1, Kazuya Arashiba1, Hiromasa Tanaka2,3, Yuki Matsuo2,3, Kazunari Nakajima1, Kazunari Yoshizawa4,5, Yoshiaki Nishibayashi6.   

Abstract

The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP-type pincer ligand. Up to 15.9 equivalents of ammonia were produced based on the amount of catalyst together with 1.0 equivalent of hydrazine (17.9 equiv of fixed nitrogen atoms).
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  ammonia; catalysis; cobalt; dinitrogen; pincer ligands

Year:  2016        PMID： 27529617     DOI： 10.1002/anie.201606090

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  20 in total

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6.  Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands.

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Journal:  Inorg Chem       Date:  2018-07-24       Impact factor: 5.165

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Journal:  Inorg Chem       Date:  2021-01-07       Impact factor: 5.165

8.  Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation.

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10.  A Lewis Base Catalysis Approach for the Photoredox Activation of Boronic Acids and Esters.

Authors:  Fabio Lima; Upendra K Sharma; Lars Grunenberg; Debasmita Saha; Sandra Johannsen; Joerg Sedelmeier; Erik V Van der Eycken; Steven V Ley
Journal:  Angew Chem Int Ed Engl       Date:  2017-10-24       Impact factor: 15.336
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