Literature DB >> 27507220

Hexanuclear tin(ii) and mixed valence tin(ii,iv) oxide clusters within polyoxometalates.

Kosuke Suzuki1, Takumi Hanaya1, Rinta Sato1, Takuo Minato1, Kazuya Yamaguchi1, Noritaka Mizuno1.   

Abstract

A hexanuclear mixed valence tin oxide cluster [Sn3(2+)Sn3(4+)O15](12-) was successfully synthesized by the solution-state selective oxidation of a tin oxide cluster [Sn6(2+)O12](12-) within trivacant lacunary polyoxometalates, where lone pairs on the Sn(2+) species acted as stereochemically active sites.

Entities:  

Year:  2016        PMID： 27507220     DOI： 10.1039/c6cc05284c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Variable control of the electronic states of a silver nanocluster via protonation/deprotonation of polyoxometalate ligands.

Authors:  Kentaro Yonesato; Seiji Yamazoe; Soichi Kikkawa; Daisuke Yokogawa; Kazuya Yamaguchi; Kosuke Suzuki
Journal:  Chem Sci       Date:  2022-04-12       Impact factor: 9.969

2.  Structure of an Ultrathin Oxide on Pt3 Sn(111) Solved by Machine Learning Enhanced Global Optimization.

Authors:  Lindsay R Merte; Malthe Kjaer Bisbo; Igor Sokolović; Martin Setvín; Benjamin Hagman; Mikhail Shipilin; Michael Schmid; Ulrike Diebold; Edvin Lundgren; Bjørk Hammer
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-29       Impact factor: 16.823
  2 in total

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