Literature DB >> 27505714

Catalytic Fehling's Reaction: An Efficient Aerobic Oxidation of Aldehyde Catalyzed by Copper in Water.

Mingxin Liu1, Chao-Jun Li2.   

Abstract

The first example of homogeneous copper-catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  copper; homogeneous catalysis; oxidation; reaction mechanisms

Year:  2016        PMID： 27505714     DOI： 10.1002/anie.201604847

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  A biocatalytic method for the chemoselective aerobic oxidation of aldehydes to carboxylic acids.

Authors:  Tanja Knaus; Vasilis Tseliou; Luke D Humphreys; Nigel S Scrutton; Francesco G Mutti
Journal:  Green Chem       Date:  2018-07-10       Impact factor: 10.182

2.  Copper-Catalyzed Vinylogous Aerobic Oxidation of Unsaturated Compounds with Air.

Authors:  Hai-Jun Zhang; Alexander W Schuppe; Shi-Tao Pan; Jin-Xiang Chen; Bo-Ran Wang; Timothy R Newhouse; Liang Yin
Journal:  J Am Chem Soc       Date:  2018-04-09       Impact factor: 15.419

3.  Computational exploration of copper catalyzed vinylogous aerobic oxidation of unsaturated compounds.

Authors:  Ting Wang; Yu Zhou; Yao Xu; Gui-Juan Cheng
Journal:  Sci Rep       Date:  2021-01-14       Impact factor: 4.379

4.  Practical scale up synthesis of carboxylic acids and their bioisosteres 5-substituted-1H-tetrazoles catalyzed by a graphene oxide-based solid acid carbocatalyst.

Authors:  Rupali Mittal; Amit Kumar; Satish Kumar Awasthi
Journal:  RSC Adv       Date:  2021-03-17       Impact factor: 3.361

5.  Solvent Effect on Product Distribution in the Aerobic Autoxidation of 2-Ethylhexanal: Critical Role of Polarity.

Authors:  Zheng Wang; Yitong Qin; Huijiang Huang; Guobing Li; Yan Xu; Peng Jin; Bo Peng; Yujun Zhao
Journal:  Front Chem       Date:  2022-03-25       Impact factor: 5.221

6.  Activating molecular oxygen with Au/CeO2 for the conversion of lignin model compounds and organosolv lignin.

Authors:  Wu-Lin Song; Qingmeng Dong; Liang Hong; Zhou-Qi Tian; Li-Na Tang; Wenli Hao; Hongxi Zhang
Journal:  RSC Adv       Date:  2019-10-02       Impact factor: 4.036

7.  Preparative microdroplet synthesis of carboxylic acids from aerobic oxidation of aldehydes.

Authors:  Xin Yan; Yin-Hung Lai; Richard N Zare
Journal:  Chem Sci       Date:  2018-05-16       Impact factor: 9.825

8.  A Supramolecular Catalyst Self-Assembled From Polyoxometalates and Cationic Pillar[5]arenes for the Room Temperature Oxidation of Aldehydes.

Authors:  Mengyan Zeng; Kun Chen; Junyan Tan; Jie Zhang; Yongge Wei
Journal:  Front Chem       Date:  2018-10-16       Impact factor: 5.221
  8 in total

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