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Literature DB >> 27499607

Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.

Jon I Day¹, Kip Teegardin¹, Jimmie Weaver¹, John Chan².

Abstract

Photocatalytic organic transformations utilizing ruthenium and iridium complexes have garnered significant attention due to the access they provide to new synthetic spaces through new reaction mechanisms. A survey of the photophysical data and the diversity of transformations that may be accomplished utilizing commercially available photocatalysts is contained herein.

Entities: Chemical Gene

Keywords: Photocatalysis; organic synthesis; photocatalysts

Year: 2016 PMID： 27499607 PMCID： PMC4972501 DOI： 10.1021/acs.oprd.6b00101

Source DB: PubMed Journal: Org Process Res Dev ISSN： 1083-6160 Impact factor: 3.317

45 in total

1. Ultrafast Photoinduced Electron Transfer from Peroxide Dianion.

Authors: Bryce L Anderson; Andrew G Maher; Matthew Nava; Nazario Lopez; Christopher C Cummins; Daniel G Nocera
Journal: J Phys Chem B Date: 2015-02-25 Impact factor: 2.991

Review 2. Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

Authors: Christopher K Prier; Danica A Rankic; David W C MacMillan
Journal: Chem Rev Date: 2013-03-19 Impact factor: 60.622

3. Combining gold and photoredox catalysis: visible light-mediated oxy- and aminoarylation of alkenes.

Authors: Basudev Sahoo; Matthew N Hopkinson; Frank Glorius
Journal: J Am Chem Soc Date: 2013-04-08 Impact factor: 15.419

4. Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids.

Authors: Lingling Chu; Jeffrey M Lipshultz; David W C MacMillan
Journal: Angew Chem Int Ed Engl Date: 2015-05-26 Impact factor: 15.336

5. Enantioselective photoredox catalysis enabled by proton-coupled electron transfer: development of an asymmetric aza-pinacol cyclization.

Authors: Lydia J Rono; Hatice G Yayla; David Y Wang; Michael F Armstrong; Robert R Knowles
Journal: J Am Chem Soc Date: 2013-11-13 Impact factor: 15.419

6. Vicinal difunctionalization of alkenes: chlorotrifluoromethylation with CF3SO2Cl by photoredox catalysis.

Authors: Se Hwan Oh; Yashwardhan R Malpani; Neul Ha; Young-Sik Jung; Soo Bong Han
Journal: Org Lett Date: 2014-02-26 Impact factor: 6.005

7. Visible-light-promoted redox neutral C-H amidation of heteroarenes with hydroxylamine derivatives.

Authors: Qixue Qin; Shouyun Yu
Journal: Org Lett Date: 2014-06-25 Impact factor: 6.005

8. Nitrogen-centered radical-mediated C-H imidation of arenes and heteroarenes via visible light induced photocatalysis.

Authors: Hyejin Kim; Taehoon Kim; Dong Gil Lee; Sang Weon Roh; Chulbom Lee
Journal: Chem Commun (Camb) Date: 2014-08-25 Impact factor: 6.222

9. Direct β-alkylation of aldehydes via photoredox organocatalysis.

Authors: Jack A Terrett; Michael D Clift; David W C MacMillan
Journal: J Am Chem Soc Date: 2014-04-29 Impact factor: 15.419

10. Redox mediators in visible light photocatalysis: photocatalytic radical thiol-ene additions.

Authors: Elizabeth L Tyson; Zachary L Niemeyer; Tehshik P Yoon
Journal: J Org Chem Date: 2014-01-27 Impact factor: 4.354

34 in total

1. Predictive Strength of Photophysical Measurements for in Vitro Photobiological Activity in a Series of Ru(II) Polypyridyl Complexes Derived from π-Extended Ligands.

Authors: Christian Reichardt; Susan Monro; Fabian H Sobotta; Katsuya L Colón; Tariq Sainuddin; Mat Stephenson; Eric Sampson; John Roque; Huimin Yin; Johannes C Brendel; Colin G Cameron; Sherri McFarland; Benjamin Dietzek
Journal: Inorg Chem Date: 2019-02-14 Impact factor: 5.165

10. Defluorodearomatization: A Photocatalytic Birch-Like Reduction That Enables C-C Bond Formation and Provides Access to Unnatural Cannabinoids.

Authors: Jon I Day; Sascha Grotjahn; Sameera Senaweera; Burkhard Koenig; Jimmie D Weaver Iii
Journal: J Org Chem Date: 2021-06-02 Impact factor: 4.354

Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.

1. Ultrafast Photoinduced Electron Transfer from Peroxide Dianion.

Review 2. Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

3. Combining gold and photoredox catalysis: visible light-mediated oxy- and aminoarylation of alkenes.

4. Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids.

5. Enantioselective photoredox catalysis enabled by proton-coupled electron transfer: development of an asymmetric aza-pinacol cyclization.

6. Vicinal difunctionalization of alkenes: chlorotrifluoromethylation with CF3SO2Cl by photoredox catalysis.

7. Visible-light-promoted redox neutral C-H amidation of heteroarenes with hydroxylamine derivatives.

8. Nitrogen-centered radical-mediated C-H imidation of arenes and heteroarenes via visible light induced photocatalysis.

9. Direct β-alkylation of aldehydes via photoredox organocatalysis.

10. Redox mediators in visible light photocatalysis: photocatalytic radical thiol-ene additions.

1. Predictive Strength of Photophysical Measurements for in Vitro Photobiological Activity in a Series of Ru(II) Polypyridyl Complexes Derived from π-Extended Ligands.

2. Synthesis of azetidines via visible-light-mediated intermolecular [2+2] photocycloadditions.

3. Solubility of Iridium and Ruthenium Organometallic Photoredox Catalysts.

4. Aza-Heterocycles via Copper-Catalyzed, Remote C-H Desaturation of Amines.

5. Regioselective Radical Amino-Functionalizations of Allyl Alcohols via Dual Catalytic Cross-Coupling.

6. Acyl Radical Chemistry via Visible-Light Photoredox Catalysis.

7. Preparation of Fac-Tris(2-Phenylpyridinato) Iridium(III).

8. Olefin-Supported Cationic Copper Catalysts for Photochemical Synthesis of Structurally Complex Cyclobutanes.

9. Organophotoredox/palladium dual catalytic decarboxylative Csp³-Csp³ coupling of carboxylic acids and π-electrophiles.

10. Defluorodearomatization: A Photocatalytic Birch-Like Reduction That Enables C-C Bond Formation and Provides Access to Unnatural Cannabinoids.