| Literature DB >> 27482769 |
Zhiyuan Huang1, Qingquan Lu1, Yichang Liu1, Dong Liu1, Jian Zhang1, Aiwen Lei1,2.
Abstract
A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.Entities:
Year: 2016 PMID： 27482769 DOI： 10.1021/acs.orglett.6b01575
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005