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Literature DB >> 27481529

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids.

Guoting Zhang¹, Lingling Zhang¹, Hong Yi¹, Yi Luo¹, Xiaotian Qi², Chen-Ho Tung³, Li-Zhu Wu³, Aiwen Lei⁴.

Abstract

An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst. The process features a low-cost metal catalyst and atom economy, which provides an appealing strategy for future synthetic chemistry.

Entities: Chemical

Year: 2016 PMID： 27481529 DOI： 10.1039/c6cc04109d

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

10 in total

Review 1. Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis.

Authors: Kitae Kwon; R Thomas Simons; Meganathan Nandakumar; Jennifer L Roizen
Journal: Chem Rev Date: 2021-10-08 Impact factor: 60.622

Review 2. Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

Authors: Shuai Liang; Kamil Hofman; Marius Friedrich; Julian Keller; Georg Manolikakes
Journal: ChemSusChem Date: 2021-10-13 Impact factor: 9.140

Review 3. Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis.

Authors: Stephanie G E Amos; Marion Garreau; Luca Buzzetti; Jerome Waser
Journal: Beilstein J Org Chem Date: 2020-05-29 Impact factor: 2.883

4. Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine.

Authors: Shengqing Zhu; Jian Qin; Fang Wang; Huan Li; Lingling Chu
Journal: Nat Commun Date: 2019-02-14 Impact factor: 14.919

5. A Photocatalytic System Composed of Benzimidazolium Aryloxide and Tetramethylpiperidine 1-Oxyl to Promote Desulfonylative α-Oxyamination Reactions of α-Sulfonylketones.

Authors: Tsukasa Tanaka; Takehiro Kiuchi; Yuuki Ooe; Hajime Iwamoto; Shin-Ya Takizawa; Shigeru Murata; Eietsu Hasegawa
Journal: ACS Omega Date: 2022-01-26

10. Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with water.

Authors: Sadhan Jana; Ajay Verma; Rahul Kadu; Sangit Kumar
Journal: Chem Sci Date: 2017-07-10 Impact factor: 9.825

10 in total

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids.

Review 1. Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis.

Review 2. Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

Review 3. Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis.

4. Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine.

5. A Photocatalytic System Composed of Benzimidazolium Aryloxide and Tetramethylpiperidine 1-Oxyl to Promote Desulfonylative α-Oxyamination Reactions of α-Sulfonylketones.

6. Copper-assisted preparation of pyridinyl sulfonate esters from hydroxypyridines and sodium sulfinates.

7. Palladium nanoparticles as efficient catalyst for C-S bond formation reactions.

Review 8. Photocatalytic formation of carbon-sulfur bonds.

9. Water-promoted C-S bond formation reactions.

10. Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with water.