Literature DB >> 27457108

Iron-Catalyzed Acylation of Polyfunctionalized Aryl- and Benzylzinc Halides with Acid Chlorides.

Andreas D Benischke1, Marcel Leroux1, Irina Knoll1, Paul Knochel1.   

Abstract

FeCl2 (5 mol %) catalyzes a smooth and convenient acylation of functionalized arylzinc halides at 50 °C (2-4 h) and benzylic zinc chlorides at 25 °C (0.5-4 h) with a variety of acid chlorides leading to polyfunctionalized diaryl and aryl heteroaryl ketones.

Entities:  

Year:  2016        PMID： 27457108     DOI： 10.1021/acs.orglett.6b01677

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Rapidly Activating Pd-Precatalyst for Suzuki-Miyaura and Buchwald-Hartwig Couplings of Aryl Esters.

Authors:  Amira H Dardir; Patrick R Melvin; Ryan M Davis; Nilay Hazari; Megan Mohadjer Beromi
Journal:  J Org Chem       Date:  2017-12-12       Impact factor: 4.354

2.  Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis.

Authors:  Javad Amani; Gary A Molander
Journal:  J Org Chem       Date:  2017-01-17       Impact factor: 4.354
  2 in total

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