| Literature DB >> 27453257 |
Andrea M Hardman-Baldwin1, Michael D Visco1, Joshua M Wieting1, Charlotte Stern1, Shin-Ichi Kondo1, Anita E Mattson1.
Abstract
Promising levels of enantiocontrol are observed in the silanediol-catalyzed addition of silyl ketene acetals to benzopyrylium triflates. This rare example of enantioselective, intermolecular chromenone functionalization with carbonyl-containing nucleophiles has potential applications in the synthesis of bioactive chromanones and tetrahydroxanthones.Entities:
Year: 2016 PMID: 27453257 DOI: 10.1021/acs.orglett.6b01783
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005