| Literature DB >> 27452528 |
Takahiro Sawano1, Zekai Lin1, Dean Boures1, Bing An2, Cheng Wang2, Wenbin Lin1,2.
Abstract
Mono(phosphine)-M (M-PR3; M = Rh and Ir) complexes selectively prepared by postsynthetic metalation of a porous triarylphosphine-based metal-organic framework (MOF) exhibited excellent activity in the hydrosilylation of ketones and alkenes, the hydrogenation of alkenes, and the C-H borylation of arenes. The recyclable and reusable MOF catalysts significantly outperformed their homogeneous counterparts, presumably via stabilizing M-PR3 intermediates by preventing deleterious disproportionation reactions/ligand exchanges in the catalytic cycles.Entities:
Year: 2016 PMID： 27452528 DOI： 10.1021/jacs.6b06239
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419