Literature DB >> 27442186

A Highly Stable Nonhysteretic {Cu2 (tebpz) MOF+water} Molecular Spring.

Yaroslav Grosu1,2,3,4, Mian Li5, Yun-Lei Peng5, Dong Luo5, Dan Li5, Abdessamad Faik4, Jean-Marie Nedelec1,2, Jean-Pierre Grolier1,2.   

Abstract

A molecular spring formed by a hydrophobic metal-organic framework Cu2 (tebpz) (tebpz=3,3',5,5'-tetraethyl-4,4'-bipyrazolate) and water is presented. This nanoporous heterogeneous lyophobic system (HLS) has exceptional properties compared to numerous reported systems of such type in terms of stability, efficiency, and operating pressure. Mechanical and thermal energetic characteristics as well as stability of the system are discussed and compared in detail with those of other previously reported HLS.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  energy conversion; heterogeneous lyophobic systems; interfaces; metal-organic frameworks; molecular devices

Year:  2016        PMID： 27442186     DOI： 10.1002/cphc.201600567

Source DB:  PubMed          Journal:  Chemphyschem        ISSN： 1439-4235            Impact factor:   3.102


  5 in total

1.  Vapor nucleation paths in lyophobic nanopores.

Authors:  Antonio Tinti; Alberto Giacomello; Carlo Massimo Casciola
Journal:  Eur Phys J E Soft Matter       Date:  2018-04-19       Impact factor: 1.890

2.  Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion-Extrusion into-from Hydrophobic Nanopores.

Authors:  Paweł Zajdel; David G Madden; Robin Babu; Marco Tortora; Diego Mirani; Nikolay Nikolaevich Tsyrin; Luis Bartolomé; Eder Amayuelas; David Fairen-Jimenez; Alexander Rowland Lowe; Mirosław Chorążewski; Juscelino B Leao; Craig M Brown; Markus Bleuel; Victor Stoudenets; Carlo Massimo Casciola; María Echeverría; Francisco Bonilla; Giulia Grancini; Simone Meloni; Yaroslav Grosu
Journal:  ACS Appl Mater Interfaces       Date:  2022-06-03       Impact factor: 10.383

3.  Intrusion and extrusion of water in hydrophobic nanopores.

Authors:  Antonio Tinti; Alberto Giacomello; Yaroslav Grosu; Carlo Massimo Casciola
Journal:  Proc Natl Acad Sci U S A       Date:  2017-11-14       Impact factor: 11.205

4.  Effect of the Topology on Wetting and Drying of Hydrophobic Porous Materials.

Authors:  Yuriy G Bushuev; Yaroslav Grosu; Mirosław A Chorążewski; Simone Meloni
Journal:  ACS Appl Mater Interfaces       Date:  2022-06-22       Impact factor: 10.383

5.  Recovering superhydrophobicity in nanoscale and macroscale surface textures.

Authors:  Alberto Giacomello; Lothar Schimmele; Siegfried Dietrich; Mykola Tasinkevych
Journal:  Soft Matter       Date:  2019-09-25       Impact factor: 3.679
  5 in total

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