| Literature DB >> 27431207 |
David E Fast1, Michal Zalibera2, Andrea Lauer3, Anna Eibel1, Caroline Schweigert4, Anne-Marie Kelterer1, Martin Spichty5, Dmytro Neshchadin1, Dominik Voll3, Hanna Ernst4, Yu Liang4, Kurt Dietliker6, Andreas-Neil Unterreiner4, Christopher Barner-Kowollik3, Hansjörg Grützmacher6, Georg Gescheidt1.
Abstract
Bis(mesitoyl)phosphinic acid and its sodium salt display a unique photo-induced reactivity: both derivatives stepwise release two mesitoyl radicals and, remarkably, metaphosphorous acid (previously postulated as transient species in the gas phase), providing a new phosphorus-based reagent.Entities:
Year: 2016 PMID： 27431207 DOI： 10.1039/c6cc05219c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222