Literature DB >> 27424868

Repeatable mechanochemical activation of dynamic covalent bonds in thermoplastic elastomers.

Keiichi Imato1, Takeshi Kanehara2, Shiki Nojima2, Tomoyuki Ohishi3, Yuji Higaki3, Atsushi Takahara4, Hideyuki Otsuka5.   

Abstract

Repeated mechanical scission and recombination of dynamic covalent bonds incorporated in segmented polyurethane elastomers are demonstrated by utilizing a diarylbibenzofuranone-based mechanophore and by the design of the segmented polymer structures. The repeated mechanochemical reactions can accompany clear colouration and simultaneous fading.

Entities:  

Year:  2016        PMID: 27424868     DOI: 10.1039/c6cc04767j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  The photoregulation of a mechanochemical polymer scission.

Authors:  Jumpei Kida; Keiichi Imato; Raita Goseki; Daisuke Aoki; Masakazu Morimoto; Hideyuki Otsuka
Journal:  Nat Commun       Date:  2018-08-29       Impact factor: 14.919

2.  Effects of Diisocyanate Structure and Disulfide Chain Extender on Hard Segmental Packing and Self-Healing Property of Polyurea Elastomers.

Authors:  Ting Li; Tianze Zheng; Jiarui Han; Zhanli Liu; Zhao-Xia Guo; Zhuo Zhuang; Jun Xu; And Bao-Hua Guo
Journal:  Polymers (Basel)       Date:  2019-05-08       Impact factor: 4.329

  2 in total

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