Literature DB >> 27411406

The organocatalytic ring-opening polymerization of N-tosyl aziridines by an N-heterocyclic carbene.

Camille Bakkali-Hassani1, Elisabeth Rieger, Joan Vignolle, Frederik R Wurm, Stéphane Carlotti, Daniel Taton.   

Abstract

The ring-opening polymerization of N-tosyl aziridines, in the presence of 1,3-bis(isopropyl)-4,5(dimethyl)imidazol-2-ylidene as an organocatalyst and an N-tosyl secondary amine as initiator mimicking the growing chain, provides the first metal-free route to well defined poly(aziridine)s (PAz) and related PAz-based block copolymers.

Entities:  

Year:  2016        PMID: 27411406     DOI: 10.1039/c6cc04323b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Nucleophilic ring opening reactions of aziridines.

Authors:  Rabia Akhtar; Syed Ali Raza Naqvi; Ameer Fawad Zahoor; Sameera Saleem
Journal:  Mol Divers       Date:  2018-05-04       Impact factor: 2.943

2.  The Anionic Polymerization of a tert-Butyl-Carboxylate-Activated Aziridine.

Authors:  Chandan Giri; Jen-Yu Chang; Pierre Canisius Mbarushimana; Paul A Rupar
Journal:  Polymers (Basel)       Date:  2022-08-10       Impact factor: 4.967

  2 in total

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