Literature DB >> 27404568

Silver Complexes of Dihalogen Molecules.

Przemysław J Malinowski1,2, Daniel Himmel1, Ingo Krossing3.   

Abstract

The perfluorohexane-soluble and donor-free silver compound Ag(A) (A=Al(OR(F) )4 ; R(F) =C(CF3 )3 ) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen-silver complexes Ag(Cl2 )A, Ag(Br2 )A, and Ag(I2 )A derived from the soluble silver compound Ag(A) (characterized by single-crystal/powder XRD, Raman spectra, and quantum-mechanical calculations).
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Raman spectroscopy; crystal structures; density functional calculations; halogen molecules; weakly coordinating anions

Year:  2016        PMID： 27404568     DOI： 10.1002/anie.201603741

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Facile and systematic access to the least-coordinating WCA [(RFO)3Al-F-Al(ORF)3]- and its more Lewis-basic brother [F-Al(ORF)3]- (RF = C(CF3)3).

Authors:  Arthur Martens; Philippe Weis; Michael Christian Krummer; Marvin Kreuzer; Andreas Meierhöfer; Stefan C Meier; Jan Bohnenberger; Harald Scherer; Ian Riddlestone; Ingo Krossing
Journal:  Chem Sci       Date:  2018-08-01       Impact factor: 9.825

2.  Towards clustered carbonyl cations [M3(CO)14]2+ (M = Ru, Os): the need for innocent deelectronation.

Authors:  Malte Sellin; Christian Friedmann; Maximilian Mayländer; Sabine Richert; Ingo Krossing
Journal:  Chem Sci       Date:  2022-07-07       Impact factor: 9.969

3.  Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals.

Authors:  Jan Bohnenberger; Manuel Schmitt; Wolfram Feuerstein; Ivo Krummenacher; Burkhard Butschke; Jakub Czajka; Przemysław J Malinowski; Frank Breher; Ingo Krossing
Journal:  Chem Sci       Date:  2020-03-06       Impact factor: 9.825

4.  Simple modification of basic dyes with bulky &symmetric WCAs for improving their solubilities in organic solvents without color change.

Authors:  Jeong Yun Kim; Tae Gyu Hwang; Sung Wun Woo; Jae Moon Lee; Jin Woong Namgoong; Sim Bum Yuk; Sei-Won Chung; Jae Pil Kim
Journal:  Sci Rep       Date:  2017-04-06       Impact factor: 4.379
  4 in total

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