| Literature DB >> 27392974 |
Mahnoush Tayebi1, Mohammad Tavakkoli Yaraki2, Azadeh Mogharei1, Mahnaz Ahmadieh1, Mohammadreza Tahriri3,4,5, Daryoosh Vashaee6, Lobat Tayebi7,8.
Abstract
In the present research, water soluble thioglycolic acid-capped CdS quantum dots (QDs) were synthesized by chemical precipitation method. The characteristics of prepared quantum dots were determined using X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The obtained results revealed that CdS QDs have 5.60 nm crystallite size, hexagonal wurtzite structure and spherical morphology with less than 10 nm diameter. The photoluminescence (PL) spectroscopy was performed in order to study the effect of the presence of starch solutions. Blue emission peaks were positioned at 488 nm and its intensity quenched by increasing the concentration of starch solutions. The result of PL quenches in range of studied concentrations (0-100 ppm) was best described by Michaelis-Menten model. The amount of Michaelis constant (Km) for immobilized α-amylase in this system was about 68.08 ppm which showed a great tendency of enzyme to hydrolyze the starch as substrate. Finally, the limit of detection (LOD) was found to be about 2.24 ppm.Entities:
Keywords: CdS QDs; Photoluminescence; Starch; Synthesis; Thioglycolic acid; α-amylase
Mesh:
Substances:
Year: 2016 PMID: 27392974 DOI: 10.1007/s10895-016-1870-8
Source DB: PubMed Journal: J Fluoresc ISSN: 1053-0509 Impact factor: 2.217