Literature DB >> 27374166

The Pauson-Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue.

Thierry León1, Elena Fernández2.   

Abstract

The first intermolecular Pauson-Khand reaction, conducted using internal alkynylboronic esters, allows the installation of the boronic ester moiety at the β-position of the cyclopentenone with total regio- and stereoselectivity.

Entities:  

Year:  2016        PMID： 27374166     DOI： 10.1039/c6cc04717c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Trimethylsilyl-Protected Alkynes as Selective Cross-Coupling Partners in Titanium-Catalyzed [2+2+1] Pyrrole Synthesis.

Authors:  Hsin-Chun Chiu; Ian A Tonks
Journal:  Angew Chem Int Ed Engl       Date:  2018-04-25       Impact factor: 15.336

2.  Recent Advances in the Pauson-Khand Reaction.

Authors:  J David Ricker; Laina M Geary
Journal:  Top Catal       Date:  2017-03-30       Impact factor: 2.910

Review 3.  Pauson-Khand reaction of fluorinated compounds.

Authors:  Jorge Escorihuela; Daniel M Sedgwick; Alberto Llobat; Mercedes Medio-Simón; Pablo Barrio; Santos Fustero
Journal:  Beilstein J Org Chem       Date:  2020-07-14       Impact factor: 2.883
  3 in total

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